The residual effects of adding 40 t ha–1 sewage sludge (SL) to a degraded soil cropped with barley were investigated after 9 and 36 months in a field experiment under semiarid conditions. The principal soil properties were apparently still affected by SL amendment 9 months after application but the effects disappeared after 36 months. With respect to control soil humic acids (HAs), the SL-HA was characterized by higher contents of S- and N-containing groups, smaller contents of acidic groups, a prevalent aliphaticity, extended molecular heterogeneity, and smaller degrees of aromatic polycondensation and humification. Amendment with SL caused an increase in N, H, S and aliphaticity contents and a decrease in C/N ratios and O and acidic functional group contents in soil HAs isolated 9 months after SL application. These effects tended to decrease after 36 months, most probably because the slightly humified SL-HA was mineralised over time through extended microbial oxidation, while only the most recalcitrant components such as S-containing and aromatic structures were partially accumulated by incorporation into soil HA. Microbial biomass, basal respiration, metabolic quotient and enzymatic activities increased in soil 9 months after SL application, possibly because of increased soil microbial metabolism and enhanced mineralisation processes. After 36 months these properties returned to values similar to those of the unamended soil, presumably due to the loss of energy sources. 相似文献
To ascertain the contaminated conditions of polycyclic aromatic hydrocarbons (PAHs) in sludge and to evaluate the risk of application of this sludge for agricultural purposes, 44 sludge samples obtained from 15 cities in the Yangtze River Delta area of China were investigated using capillary gas chromatography/mass spectrometry (GC/MS) after ultrasonic extraction and silica gel cleanup. PAHs' contents ranged from 0.0167 to 15.4860 mg kg^-1 (dry weight, DW) and averaged 1.376 mg kg^-1, with most samples containing 〈 1.5 mg kg^-1. Pyrene (PY), fluoranthene (FL), benzo[b]fluoranthene (BbF), indeno[1,2,3-cd]pyrene (IND), benzo[a]pyrene (B[a]P), and benzo[g,h,i]perylene (BghiP) were the most dominant compounds, ranging from 0.1582 to 0.2518 mg kg^-1. Single PAH, such as naphthalene (NAP, 2-benzene rings), phenanthrene (PA, 3-benzene rings), PY (4-benzene rings), and FL (3-benzene rings), had high detection rates (76.1%-93.5%). The distribution patterns of PAHs were found to vary with the sludge samples; however, the patterns showed that a few compounds with 2- and 3-benzene rings were commonly found in the samples, whereas those with 4-, 5-, and 6-benzene rings were usually less commonly found. All the 44 sludge samples were within the B[a]P concentration limit for sludge applied to agricultural land in China (〈 3.0 rag kg^-1). The probable sources of PAH contamination in the sludge samples were petroleum, petroleum products, and combustion of liquid and solid fuel. The concentrations and distributions of the 16 PAHs in sludge were related to sludge type, source, and treatment technology, together with the physicochemical properties. 相似文献
Sewage sludge (SS), a highly heterogeneous semisolid fraction of sewage water (about 1% of the sewage water), contains various amounts of nitrogen (N) and phosphorus (P) as well as trace elements such as cadmium (Cd), lead (Pb), copper (Cu), nickel (Ni) and zinc (Zn) with extremely variable physical and chemical compositions. Application of SS improves soil properties, increases yield and simultaneously increases trace metal content in soil and plants. The difficulty in handling, transporting and applying SS and its adverse effect, especially trace metal content in soil and plant, can be overcome by SS–coir pith pelletization (SSCP) or mixing with sewage sledge–coir pith mixture (SSCM). A study was undertaken to evaluate the prepared SSCM and SSCP (1:1 ratio of SS and coir pith) along with SS on dry matter yield, trace metal content in soil and plant parts. The results showed that increased rates of application of SS or SSCM or SSCP increased the green and dry fodder yield of forage maize. Application of SS as either SSCM or SSCP at 1.2 and 2.4 g pot?1 significantly reduced the trace metal content diethylene triamine pentaacetic acid (DTPA extractable) in soil and plant parts (leaves steam and root) compared to SS application. Therefore, in order to reduce the bioavailability of trace metal in soil and its uptake by plant, application of SSCM or SSCP at 1.2 or 2.4 g pot?1 proved to be a better option than SS application. 相似文献
The aerobic batch composting fermentations of sewage sludge with wood chips and maturity compost as co-composting additives were carried out in an open type lab-scale reactor. Fourier transform infrared spectroscopy (FT-IR) spectroscopy was used to monitor the composting process, evaluate the degradation rate and thus determine the maturity. Although the composition of the input mixture strongly affects the shape of the infrared (IR) spectra, typical bands of components can be selected and used to follow the composting process.
The appearance, shape and intensity of the nitrate band at 1384 cm− 1 was well pronounced and evident for a sewage sludge-based compost maturity. An increase of the peak ratio 1384 / 2925 and decrease of 2925 / 1034, 1034 / 1384 correlated with the degree of decomposition. For the composting mixture under study the peak ratios 1034 / 1384 and 1384 / 2925 were more demonstrative. Considering the influence of the composting mixture (components and their ratio) on the shape of the FT-IR spectra the nitrate band at 1384 cm− 1 can be overlapped by other absorption bands (e.g. lignin bands in 1300–1400 cm− 1 region) thus appearing in the spectra as a shoulder, and therefore the ratios 1384 / 2925 and 1034 / 1384 become unusable to evaluate the maturity.
FT-IR spectroscopy is a quick and useful method to monitor the composting process; however any particular composting mixture needs preliminary studies of the spectra. Consequently, the most appropriate criteria describing the process (e.g. band ratios, shape and intensity of nitrate band) should be selected and the time / peak ratio curves recorded for a compost mixture under study. Afterwards monitoring of the composting process can be based on the comparison of the controls and definite samples. 相似文献